Add pork chops to non-aluminum container. Add olive oil, vinegar, Adobo, garlic, black pepper and oregano to container. Using hands, rub seasonings into pork. Cover; transfer to refrigerator. Marinate at least 2 hours, or up to 48 hours. Bring pork chops to room temperature 30 minutes before cooking.
Add 1½” corn oil to large, deep skillet. Heat oil over medium-high heat until hot, but not smoking. Add pork chops. Cook,. flipping once, until dark golden brown on both sides and cooked through (internal temperature of 150°F), 8-10 minutes total. Using tongs, transfer pork chops to paper towel-lined plate to drain.
Serve pork chops with rice and beans.